SF4

Sulfur tetrafluoride
Sulfur tetrafluoride
Sulfur tetrafluoride
Sulfur tetrafluoride
IUPAC nameSulfur(IV) fluoride
Other namesSulfur tetrafluoride
Identifiers
CAS number7783-60-0
RTECS numberWT4800000
Properties
Molecular formulaSF4
Molar mass108.07 g/mol
Appearancecolorless gas
Density1.95 g cm−3, −78 °C
Melting point

−121.0 °C

Boiling point

−38 °C

Solubility in waterdecomp
Structure
Coordination
geometry
C2v
Dipole moment0.632 D
Hazards
Main hazardshighly toxic
corrosive
NFPA 704
0
4
2
W
R-phrases14-26-34-37
S-phrases26-36/37/39-38-45
Related compounds
Related compoundsSeF4
SF6
SCl2
S2Cl2
Me2NSF3
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)
Infobox references

Sulfur tetrafluoride is the chemical compound with the formula SF4. This species exists as a gas at standard conditions. It is a corrosive species that releases dangerous HF upon exposure to water or moisture. Despite these unwelcome characteristics, this compound is a useful reagent for the preparation of organofluorine compounds, some of which are important in the pharmaceutical and specialty chemical industries. Aside from SF4, two other binary sulfur fluorides are well known, SF6 and S2F10.

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SF4

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